X-rays are radiated by matter hotter than one million Kelvin, and high-resolution X-ray spectroscopy can tell us about the composition of the matter and how fast and in what direction it is moving. Quantum calorimeters are opening this new window on the Universe. First promised four decades ago, the quantum-calorimeter era of X-ray astronomy has finally dawned.

Electronic chip with wire bonds and a central square of 36 gray squares, situated atop a gold rectangle secured with screws.Photo of the XRISM/Resolve quantum-calorimeter array in its storage container prior to integration into the instrument. The 6×6 array, 5 mm on a side, consists of independent detectors – each one a thermally isolated silicon thermistor with a HgTe absorber. The spectrometer consisting of this detector and other essential technologies separates astrophysical X-ray spectra into about 2400 resolution elements, which can be thought of as X-ray colors.NASA GSFC A quantum calorimeter is a device that makes precise measurements of energy quanta by measuring the temperature change that occurs when a quantum of energy is deposited in an absorber with low heat capacity. The absorber is attached to a thermometer that is somewhat decoupled from a heat sink so that the sensor can heat up and then cool back down again. To reduce thermodynamic noise and the heat capacity of the sensor, operation at temperatures less than 0.1 K is required. 

The idea for thermal measurement of small amounts of energy occurred in several places in the world independently when scientists observed pulses in the readout of low-temperature thermometers and infrared detectors. They attributed these spurious signals to passing cosmic-ray particles, and considered optimizing detectors for sensitive measurement of the energy of particles and photons.

The idea to develop such sensors for X-ray astronomy was conceived at Goddard Space Flight Center in 1982 when X-ray astronomers were considering instruments to propose for NASA’s planned Advanced X-ray Astrophysics Facility (AXAF). In a fateful conversation, infrared astronomer Harvey Moseley suggested thermal detection could offer substantial improvement over existing solid-state detectors. Using Goddard internal research and development funding, development advanced sufficiently to justify, just two years later, proposing a quantum-calorimeter X-ray Spectrometer (XRS) for inclusion on AXAF. Despite its technical immaturity at the time, the revolutionary potential of the XRS was acknowledged, and the proposal was accepted.

The AXAF design evolved over the subsequent years, however, and the XRS was eliminated from its complement of instruments. After discussions between NASA and the Japanese Institute of Space and Astronautical Science (ISAS), a new XRS was included in the instrument suite of the Japanese Astro-E X-ray observatory. Astro-E launched in 2000 but did not reach orbit due to an anomaly in the first stage of the rocket. Astro-E2, a rebuild of Astro-E, was successfully placed in orbit in 2005 and renamed Suzaku, but the XRS instrument ceased operation before observations started due to loss of the liquid helium, an essential part of the detector cooling system, caused by a faulty storage system.

A redesigned mission, Astro-H, that included a quantum-calorimeter instrument with a redundant cooling system was successfully launched in 2016 and renamed Hitomi. Hitomi’s Soft X-ray Spectrometer (SXS) obtained high resolution spectra of the Perseus cluster of galaxies and a few other sources before a problem with the attitude control system caused the mission to be lost roughly one month after launch. Even so, Hitomi was the first orbiting observatory to obtain a scientific result using X-ray quantum calorimeters. The spectacular Perseus spectrum generated by the SXS motivated yet another attempt to implement a spaceborne quantum-calorimeter spectrometer.

The X-ray Imaging and Spectroscopy Mission (XRISM) was launched in September 2023, with the spectrometer aboard renamed Resolve to represent not only its function but also the resolve of the U.S./Japan collaboration to study the Universe through the window of this new capability. XRISM has been operating well in orbit for over a year.  

Development of the Sensor Technology Development of the sensor technology employed in Resolve began four decades ago. Note that an X-ray quantum-calorimeter spectrometer requires more than the sensor technology. Other technologies, such as the coolers that provide a